Reflux / relief

Name the case that sized your relief valve

A relief valve is a spring-loaded door on a vessel. Sizing it is not the hard part. The hard part is the list: every believable thing that could raise the pressure, each one sized on its own, and the biggest one wins. You never add them, because two disasters do not happen in the same second. This page is that list as a checklist, the fire case as a calculator, and one incident where the valve was the right size and was not connected.

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01 A spring-loaded door, in section 02 The scenario list, as a checklist 03 The fire case, and a calculator 04 Load per case, then the orifice 05 The valve that was the right size
01

A spring-loaded door, in section

The mechanism is one sentence. A spring holds a disc down onto a nozzle. When the pressure under the disc beats the spring, the disc lifts and the vessel dumps to the flare until the pressure stops rising. The set pressure is the spring. The orifice is the nozzle bore, and it is the only number the whole calculation is trying to find.

nozzle · the orifice disc spring = set pressure to flare from the vessel
A conventional spring-loaded pressure relief valve in section, drawn lifted. The nozzle bore is the orifice area the calculation sizes; the blowdown rings set how far the pressure has to fall before it reseats.

Set pressure may not be above the MAWP. A single valve on a non-fire case may accumulate to 110% of MAWP while relieving; multiple valves 116%; the fire case 121%. The relieving pressure, not the set pressure, is what the orifice equation takes.

02

The scenario list, as a checklist

Run this on any vessel. The point is not to find one answer, it is to be able to say out loud why the other five are smaller. Tick each one when you have either sized it or written down why it cannot happen here.

0 of 6 considered

The largest single case governs. Not the sum. A valve sized for the sum of six cases is grossly oversized for every one of them, and an oversized valve chatters: it opens, the flow through an orifice far larger than the load needs drops the pressure instantly, it slams shut, and it does that a few times a second until the seat and the guide are destroyed. The oversizing is not conservative. It is the failure.

03

The fire case, and a calculator

The case that usually wins is a fire nobody lit. If a pool fire burns under a vessel, the heat going into the liquid is set by the wetted surface, counted only up to 7.6 m (25 ft) above grade. Above that height the flame is not considered to reach the wall.

3.5 m A = 23.2 m2 2.0 m drum, half full every wetted square metre counts 24 m column the rule cuts it at 7.6 m 68% of the wall is dead to the fire 7.6 m above this the fire does not reach the wall
One scale, two vessels. A 2.0 m drum on a 1.5 m saddle tops out at 3.5 m, so the rule never bites and every wetted square metre counts. On a 24 m column the rule cuts at 7.6 m and 68% of the wall is dead to the fire.
Q = 21,000 F A^0.82 Btu/h
W = Q / L kg/h of vapour F is the environment factor, 1.0 for a bare vessel. 21,000 assumes adequate drainage and firefighting; without them the coefficient is 34,500. A is the wetted area in square feet. L is the latent heat at the relieving pressure, which falls as you approach the critical point, so a light hydrocarbon near its critical pressure gives a much larger vapour rate than its atmospheric latent heat suggests.
Heat in1.94e6Btu/h
Heat in569kW
Vapour9,523kg/h
OrificeH468 of 506 mm2

23.2 m2 is a 2.0 m by 6.0 m drum at half level, heads included.

Orifice from API 520 critical vapour flow at 250 psig MAWP, 110% accumulation, propane: k 1.13, M 44.1, Z 0.78, T 328 K, Kd 0.975. Change the fluid and the orifice moves; the heat input does not.

04

Load per case, then the orifice

Every case becomes a mass flow, every mass flow becomes an area, and the largest area picks a letter off the API 526 series. For the 2.0 m by 6.0 m propane drum above:

CaseRelief loadArea requiredAPI 526
blocked outlet3,200 kg/h157.2 mm2F (198)
inlet valve fails open5,400 kg/h265.2 mm2G (325)
tube rupture4,100 kg/h201.4 mm2G (325)
thermal expansion114 L/h0.5 mm2D (71)
utility failure6,200 kg/h304.5 mm2G (325)
pool fire9,523 kg/h467.7 mm2H (506)
size the door for each case on its own every circle is drawn at its true area F 198 mm2 blocked outlet 3,200 kg/h G 325 mm2 inlet valve fails open 5,400 kg/h G 325 mm2 tube rupture 4,100 kg/h D 71 mm2 thermal expansion 114 L/h G 325 mm2 utility failure 6,200 kg/h H 506 mm2 pool fire 9,523 kg/h add them: L, 1841 mm2 is 3.6x too big
The same six answers, drawn at true relative area: the radius of each circle is proportional to the square root of its orifice area, so the picture is the argument. Thermal expansion needs 0.52 mm2 and the smallest body made is 71 mm2, which is why a thermal relief valve is always enormously oversized and it does not matter.
largest single case 468 mm2 → H (506 mm2)
the sum of all six 1,397 mm2 → L (1,841 mm2) Adding them buys 3.6 times the orifice area, and a valve that chatters on every case it was bought to protect against.
05

The valve that was the right size

A correctly sized relief valve only works if it is connected. In 2013 a plant added two block valves between a reboiler and its relief valve so the reboiler could be cleaned online, and left them shut. There was then no path from the shell to the valve.

column liquid down reboiler propane boiling on the shell side vapour space hot water in relief valve the right size to flare two block valves added so it could be cleaned online LEFT SHUT 2 killed · 167 injured
The reboiler, its relief valve, and the two block valves that were added between them. Hot water in the tubes, propane on the shell, and no path out.
  1. Two block valves are added between the reboiler and its relief valve, so that a fouled reboiler can be isolated and cleaned while the unit keeps running.

  2. The reboiler is standing idle and isolated, with propane trapped on the shell side and both block valves shut. Neither valve is on any check that would have caught it.

  3. Hot water is admitted to the tubes. The trapped propane boils. The pressure has nowhere to go, because the only relief path is behind two shut gate valves.

  4. The shell ruptures and the released propane ignites.

  5. Two people are killed and 167 are injured. The relief valve was correctly sized for this vessel. It was simply not connected to it.

The lesson is not about sizing. It is that a relief path is a system, and every block valve in that path is a way to delete the valve without removing it. If a block valve has to exist, it is car-sealed or locked open and it is on a checklist somebody signs.

The simulator does the flash. It will not do the listing.

Any process simulator will flash a stream at 110% of MAWP and tell you the vapour rate to four decimal places. Not one of them will tell you that a tube rupture is credible on this exchanger, or that the line you just blocked in is liquid full. That judgment is the work, and it is the layer we are building at Reflux: the model does the arithmetic, you keep the listing.

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