From a fourth-year capstone · oxy-fuel cement

Cement is 8 percent of global emissions, and the fuel is not the main problem

Reflux on the left, Aspen Plus on the right: a two-stage condensate stabiliser built and run from one sentence. Unedited except for the waiting.

The CO2 does not mostly come from what the kiln burns. It comes out of the limestone itself, so swapping the fuel leaves most of the emission exactly where it was. My fourth-year capstone team designed around that instead of against it.

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01

The emission is the chemistry

Making clinker means cooking limestone, calcium carbonate, into lime. That reaction releases CO2 no matter what you burn, and the kiln runs above 1400 °C to do it. Swap the fuel and most of the emission is still there.

02

The design

A cryogenic air separation unit supplies pure oxygen. The kiln burns its fuel in oxygen instead of air, so the exhaust is nearly pure CO2 rather than CO2 diluted in nitrogen. That stream is purified, compressed until it goes supercritical, and injected into carbonate rock, where it slowly reacts back into carbonate. The existing kiln stays.

03

Why there are no numbers here

My team designed this for a real cement producer under NDA, so the plant, the tonnes and the dollars stay in the report. What is public is the shape of the answer: capture at the kiln, do not rebuild the kiln, and put the carbon back where the limestone came from.

A cryogenic air separation unit, drawn by my team for a hypothetical process.

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